Persistence Polymers

Degradation of Polymers

The study of biodegradation of polymers and microplastics in environmental compartments such as soil, sediments of water is important for the regulatory ssessment of the persistency of these compounds in the environment.

Fraunhofer IME has an extensive experience in performance of environmental simulation studies on the biodegradation and fate of polymers. Our focus in these activities is on the adaption and modification of the applied test protocols for the specific challenges associated with the testing of polymers, e.g. defining new polymer-specific endpoints for regulatory assessment of biodegradation beyond mineralization.

We offer standard and specifically adapted studies on the degradation of polymers in soil, water/sediment systems, water or waste water treatment simulations in accordance with current test guidelines (e.g. OECD TG 307, 308, 309, 314B). For these purposes, we are using in-house synthesized radiolabeled polymers in cooperation with Fraunhofer IAP, as these materials are generally not commercially available. In addition, state-of-the art instrumentation for polymer and plastics analysis and characterization is available to support this research.

Additional Information

Publication

Hahn S., Hennecke, D.

What can we learn from biodegradation of natural polymers for regulation?

(2023) Environmental Sciences Europe

Project

LRI-ECO64: IMPROVING LABORATORY BASED POLYMER BIODEGRADATION EVALUATIONS

 

Currently, the ECHA persistence schema includes a biodegradation screening evaluation with the option of moving to higher-tier simulation tests.  All these tests were designed for low molecular weight, soluble test materials but some have been applied to non-soluble and poorly soluble chemicals and polymers (modifications are needed for some methods and some polymer classes). Due to ECHA’s renewed interest in the evaluation of polymeric materials, there is much discussion about the applicability of standardized biodegradation test methods to polymers.

 

iMulch

An investigation of the influence (fate and effect) of polymers on a terrestrial ecosystem using the example of mulch films used in agriculture” examined possible negative effects of this development from a multi-perspective approach.

Publication

Hennecke D., Bauer A., Herrchen M., Wischerhoff E., Gores F.
Cationic polyacrylamide copolymers (PAMs): environmental half life determination in sludge-treated soil
(2018) Environmental Sciences Europe